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Phase diagrams of the Tb-Ag-In and Dy-Ag-In systems at 870 K

Identifieur interne : 001711 ( Main/Repository ); précédent : 001710; suivant : 001712

Phase diagrams of the Tb-Ag-In and Dy-Ag-In systems at 870 K

Auteurs : RBID : Pascal:12-0344584

Descripteurs français

Pascal (Inist)
- Diagramme phase, Equilibre phase, Système ternaire, Effet concentration, Diffraction RX, Spectrométrie dispersive, Spectre RX, Section isotherme, Composé ternaire, Structure cristalline, Groupe espace, Solution solide, Composé binaire, Indium, Argent, Dysprosium, Chlorure de césium, Terbium, CsCl, Tb, In, 8130B, 6166.
Wicri :
- concept : Argent.

English descriptors

KwdEn :
- Binary compounds, Cesium chloride, Crystal structure, Dispersive spectrometry, Dysprosium, Indium, Isothermal section, Phase diagrams, Phase equilibria, Quantity ratio, Silver, Solid solutions, Space groups, Terbium, Ternary compounds, Ternary systems, X-ray spectra, XRD.

Abstract

The phase equilibria of Tb-Ag-In and Dy-Ag-In ternary systems have been studied at 870 K in the whole concentration range by means of X-ray powder, single crystal X-ray diffraction and EDX analyses. Isothermal sections of Tb-Ag-In and Dy-Ag-In phase diagrams at this temperature have been constructed. Both systems are characterized by formation of three ternary compounds: REAg₃In₃ (YbAg₂In₄-type, space group Im-3), REAg₂In (MnCu₂Al-type, space group Fm-3m) and RE₂AgIn₃ (Caln₂-type, space group P6₃/mmc) RE=Tb, Dy. Homogeneity ranges of the ternary phases with CaIn₂ structure type lies from 35 to 60 at% of In for Tb-containing phase and from 39 to 50 at% of In for Dy-containing phase. The existence of solid solutions based on REAg (CsCl-type, space group Pm-3m) binary compounds up to 30 at% of In and REIn₃ (AuCu₃-type, space group Pm-3 m) binary compounds up to 5 at% of Ag has been found.

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Pascal:12-0344584

Le document en format XML

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<author><name sortKey="Demchyna, M" uniqKey="Demchyna M">M. Demchyna</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Faculty of Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodiya Str. 6</s1>
<s2>UA-79005 Lviv</s2>
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<author><name sortKey="Belan, B" uniqKey="Belan B">B. Belan</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Faculty of Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodiya Str. 6</s1>
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<author><name sortKey="Manyako, M" uniqKey="Manyako M">M. Manyako</name>
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<author><name sortKey="Pietraszko, A" uniqKey="Pietraszko A">A. Pietraszko</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, PO Box 1410</s1>
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<author><name sortKey="Kalychak, Ya" uniqKey="Kalychak Y">Ya. Kalychak</name>
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<title level="j" type="abbreviated">J. solid state chem. : (Print)</title>
<title level="j" type="main">Journal of solid state chemistry : (Print)</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Binary compounds</term>
<term>Cesium chloride</term>
<term>Crystal structure</term>
<term>Dispersive spectrometry</term>
<term>Dysprosium</term>
<term>Indium</term>
<term>Isothermal section</term>
<term>Phase diagrams</term>
<term>Phase equilibria</term>
<term>Quantity ratio</term>
<term>Silver</term>
<term>Solid solutions</term>
<term>Space groups</term>
<term>Terbium</term>
<term>Ternary compounds</term>
<term>Ternary systems</term>
<term>X-ray spectra</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Diagramme phase</term>
<term>Equilibre phase</term>
<term>Système ternaire</term>
<term>Effet concentration</term>
<term>Diffraction RX</term>
<term>Spectrométrie dispersive</term>
<term>Spectre RX</term>
<term>Section isotherme</term>
<term>Composé ternaire</term>
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<term>Solution solide</term>
<term>Composé binaire</term>
<term>Indium</term>
<term>Argent</term>
<term>Dysprosium</term>
<term>Chlorure de césium</term>
<term>Terbium</term>
<term>CsCl</term>
<term>Tb</term>
<term>In</term>
<term>8130B</term>
<term>6166</term>
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<front><div type="abstract" xml:lang="en">The phase equilibria of Tb-Ag-In and Dy-Ag-In ternary systems have been studied at 870 K in the whole concentration range by means of X-ray powder, single crystal X-ray diffraction and EDX analyses. Isothermal sections of Tb-Ag-In and Dy-Ag-In phase diagrams at this temperature have been constructed. Both systems are characterized by formation of three ternary compounds: REAg<sub>3</sub>
In<sub>3</sub>
 (YbAg<sub>2</sub>
In<sub>4</sub>
-type, space group Im-3), REAg<sub>2</sub>
In (MnCu<sub>2</sub>
Al-type, space group Fm-3m) and RE<sub>2</sub>
AgIn<sub>3</sub>
 (Caln<sub>2</sub>
-type, space group P6<sub>3</sub>
/mmc) RE=Tb, Dy. Homogeneity ranges of the ternary phases with CaIn<sub>2</sub>
 structure type lies from 35 to 60 at% of In for Tb-containing phase and from 39 to 50 at% of In for Dy-containing phase. The existence of solid solutions based on REAg (CsCl-type, space group Pm-3m) binary compounds up to 30 at% of In and REIn<sub>3</sub>
 (AuCu<sub>3</sub>
-type, space group Pm-3 m) binary compounds up to 5 at% of Ag has been found.</div>
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<fA08 i1="01" i2="1" l="ENG"><s1>Phase diagrams of the Tb-Ag-In and Dy-Ag-In systems at 870 K</s1>
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<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
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<fA14 i1="02"><s1>W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, PO Box 1410</s1>
<s2>50-950 Wroclaw</s2>
<s3>POL</s3>
<sZ>4 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>The phase equilibria of Tb-Ag-In and Dy-Ag-In ternary systems have been studied at 870 K in the whole concentration range by means of X-ray powder, single crystal X-ray diffraction and EDX analyses. Isothermal sections of Tb-Ag-In and Dy-Ag-In phase diagrams at this temperature have been constructed. Both systems are characterized by formation of three ternary compounds: REAg<sub>3</sub>
In<sub>3</sub>
 (YbAg<sub>2</sub>
In<sub>4</sub>
-type, space group Im-3), REAg<sub>2</sub>
In (MnCu<sub>2</sub>
Al-type, space group Fm-3m) and RE<sub>2</sub>
AgIn<sub>3</sub>
 (Caln<sub>2</sub>
-type, space group P6<sub>3</sub>
/mmc) RE=Tb, Dy. Homogeneity ranges of the ternary phases with CaIn<sub>2</sub>
 structure type lies from 35 to 60 at% of In for Tb-containing phase and from 39 to 50 at% of In for Dy-containing phase. The existence of solid solutions based on REAg (CsCl-type, space group Pm-3m) binary compounds up to 30 at% of In and REIn<sub>3</sub>
 (AuCu<sub>3</sub>
-type, space group Pm-3 m) binary compounds up to 5 at% of Ag has been found.</s0>
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<s5>11</s5>
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<s5>12</s5>
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<s5>13</s5>
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<s2>NC</s2>
<s5>14</s5>
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<s2>NC</s2>
<s5>14</s5>
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<s2>NC</s2>
<s5>15</s5>
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<s2>NC</s2>
<s5>15</s5>
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<s2>NC</s2>
<s5>16</s5>
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<s2>NC</s2>
<s5>16</s5>
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<s5>17</s5>
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<s2>NC</s2>
<s5>18</s5>
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<s2>NC</s2>
<s5>18</s5>
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<fC03 i1="19" i2="3" l="FRE"><s0>CsCl</s0>
<s4>INC</s4>
<s5>46</s5>
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<fC03 i1="20" i2="3" l="FRE"><s0>Tb</s0>
<s4>INC</s4>
<s5>47</s5>
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<fC03 i1="21" i2="3" l="FRE"><s0>In</s0>
<s4>INC</s4>
<s5>48</s5>
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<fC03 i1="22" i2="3" l="FRE"><s0>8130B</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fC03 i1="23" i2="3" l="FRE"><s0>6166</s0>
<s4>INC</s4>
<s5>72</s5>
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Phase diagrams of the Tb-Ag-In and Dy-Ag-In systems at 870 K

Phase diagrams of the Tb-Ag-In and Dy-Ag-In systems at 870 K

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri